Simplifying the theory of the Invar effect in iron-nickel alloys
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Zero-temperature ab initio calculations of the lattice spacing of
disordered iron-nickel alloys are presented. These show a strong negative
correlation between the lattice spacing and the number of
nearest-neighbour iron-iron pairs with antiparallel local moments. Based
on the conjecture that this correlation persists at non-zero temperature,
a simple theory is formulated that reproduces several experimental results
on this class of Invar materials. We conclude that an alloy shows the
Invar effect if the concentration of such pairs increases sufficiently
rapidly over a broad interval of temperature.
Some of this work is available as a preprint, arXiv:0811.3673.
This talk is part of the Irregular seminars in TCM series.
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